From June 2015 patent expires so far, domestic enterprises to obtain pyraclostrobin pesticide registration documents has reached 261, of which 53 original drugs, 208 preparations, the market capacity of 1 billion US dollars level, just two years Burst a variety of 10 million large items, the hot situation is still continuing, a large number of enterprises to take this opportunity to quickly layout, mercilessly enjoy a pyrazole mushroom brought about the market dividend.
Polyglutamic acid agricultural grade |
It is noteworthy that, with the continuous increase in production capacity and increased market competition, pyraclostrobin will eventually go to conventional. Faced with the domestic agricultural market continued to slump, the next five years which products can successfully take over the development of the domestic market for power. Xiaobian several promising market prospects of the “potential shares” were sorted out.
Polyglutamic acid 30% agricultural grade |
Prothioconazole
Prothiopsis is a triazole thione fungicide developed, produced and produced by Bayer CropScience, which is listed in 2004 and has $ 800 million in sales in 2015. It has become the chief product of Bayer, the world’s leading fungicide In the third largest product, the first major product of cereal fungicide market, the fourth largest product in the field of soybean fungicide. In the 10 years between 2005 and 2015, the annual growth rate of procyanidazole was 21.6%, showing its strong market vitality.
In 2015, among the world’s leading fungicides, propoxazole ranks third in sales of $ 8 billion, with azoxystrobin ($ 1.305 billion) and pyrazole $ 850 million).
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As of April 2017, there have been 84 prothioconazole products in China won the field test approval certificate. These products, both a single product, there are complex products. Compatible products include: azoxystrobin, pyrazole bacteria bacteria, oxime fungus, picolorate, fluoxibenolide, tebuconazole, metformatum, fine metalaxyl and amino oligosaccharides. Field crops include: rice, wheat, corn, peanuts, cucumbers and tomatoes.
Fluoxazole aniline
Fluoxacillanilide is a pyrazole amide fungicide developed, developed and produced by Bayer Corporation, which is another succinate dehydrogenase inhibitor (SDHI) bactericide developed after Bayer Bipyridamole, and With a suction, prevention and treatment, long lasting. It is mainly used as a bactericidal seed treatment agent. After seed treatment, the medicine penetrates into the germinated seeds and is transmitted to the whole plant through the xylem of the young plant, thereby protecting the growing seedlings at a high level. The product can be widely under low doses of Basidiomycetes and Ascomycetes and other pathogens caused by the disease.
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Fluoxacillanilide is developed in addition to the seed treatment agent and can also be applied in soil. All treatments can effectively protect the seedlings of corn, soybean, rape, potato, cotton, peanut, onion and legumes from seed and soil-borne diseases caused by Rhizoctonia solani in Basidiomycetes and can also be effective Prevention and control of cereal crops caused by the black fungus, Rhizoctonia and cyclococcus bacteria caused by the disease.
SDHI fungicides, although the market is developing rapidly, but the higher the risk of resistance. To this end, Bayer not only developed a number of single products of fluoxetine aniline, but also developed a lot of complex products of fluoxacillin aniline, such as fluoxetine aniline + prothioconazole, fluoxetine aniline + thiamethoxam, Fluoxetine aniline + oxytetracycline, fluoxetine aniline + imidacloprid, fluoxazole aniline + prothioconazole + metalaxyl, fluoxazole aniline + prothioconazole + thiamethoxam, fluoxacillin an Creamer + thiamethoxazole and oxime strains.
Benzenone
Phenosterone was first created in 1998 by the United States Cyanamide Company (now BASF), developed by BASF. 2004 was the first to register in the UK market, after 10 years or so in China debut. In the world, its market sales since the market gradually expanded, from 2004 to 2009, the average annual growth rate of up to 90.4%, 2012 sales of about 70 million US dollars. The current development of the main products mainly to suspending agent, the development of goods including ” Flexity, Vivando, and the domestic Ying Teng.
Gamma Polyglutamic acid food grade |
Mechanism and bright spot: Benzenone is benzophenone fungicide, mainly through the interference of pathogenic bacteria spore germination of the development and formation of the attachment of bacteria, inhibit the spore germination of powdery mildew, control the spread of disease. At the same time, probenone can interfere with the formation and formation of polar actin tissue, so that the formation of the mycelium of the mycelia of the bacteria by the interference and inhibition, thus hindering the normal growth and growth of mycelium, inhibit and inhibit the white powder Pathogens against the effective control of the hazards of powdery mildew, with significant prevention and treatment.
Application: Benzenone has several times higher than the azoxycarboxylamine bactericidal activity, with those with dimethylation of the inhibitor and aniline pyrimidine fungicide no cross-resistance, can be used for cereals, grapes, cucumber , Beans, strawberries and other crops powder control.
Benzoyl amide
gamma polyglutamic acid fertiliser(fertilizer) grade |
Polyacetamide bacteria currently have 93% of the original drug, 23.4% diacetamide fungus suspension agent, 440 grams / liter of bifendate and chlorothalonil suspension and other related registration, are Syngenta all for the prevention and treatment Tomato late blight, pepper blight, litchi tree frosty mold, potato late blight, grape downy mildew, watermelon disease and so on.
The diacetamide fungi are amide fungicides. Its mechanism of action for the inhibition of phospholipid biosynthesis, the vast majority of the bacteria caused by the leaves and fruit diseases are very good control effect. Spore at the germination stage has a high activity, and can inhibit mycelial growth and spore formation. Can be quickly absorbed through the leaves, and stay in the leaf surface wax layer, the protection of the leaves. The results showed that the 250 g / L suspending agent had good control effect on Phytophthora infestans. The recommended dose had no adverse effect on the growth of litchi tree, and no phytotoxicity occurred.
In 2011, the global sales of hundreds of millions of dollars of pesticide varieties and sales, diacetyl fungi 100 million US dollars
Isothiamine
Gamma Polyglutamic acid Cosmetic |
Isothiamine is Bayer and Sumitomo Chemical Co., Ltd. jointly developed for the prevention and treatment of rice blast isothiazole fungicides. It is characterized by its direct antibacterial effect on pathogens, but by stimulating the rice itself to the natural defense mechanism of rice blast, to achieve the purpose of resistance to rice blast. Bayer noted that this is the first example of an active ingredient that has a low resistance to the effect of inducing resistance. This environmentally friendly product is well suited for use in rice growth processes and has some insecticidal activity.
Isothiazole formamides include isothiamine and the like in plant with strong plant-inducing activity, prophylactic administration or early use in the early stages of the disease, a variety of biological factors and abiotic factors can activate the plant’s own defensive resistance that System induced resistance, and affect the pathogen life history of multiple links, so that the plant on a variety of fungi, bacteria, insects and viruses produce broad-spectrum self-protection. Isothiomide also has a strong microbicidal activity, for direct control of Rhizoctonia, Fungi, fungi, bacteria, subclasses, Ascomycetes, Basidiomycetes and semi-known bacteria class. Isotiamines are particularly useful for the prevention and control of cereal diseases such as the type of powdery mildew, the type of rice blast, or the prevention of viticulture and the growth of fruits and vegetables.
gamma polyglutamic acid agriculture grade |
Flutamide
Fluoropyrazine is a new type of pyridine amide fungicide developed by Bayer CropScience, Germany. It is mainly used to control common pathogens on various vegetables and grapes, such as downy mildew, blight, late blight, damping-off Etc., with protective and broad-spectrum therapeutic effects.
Fluoropyramide mainly acts on the specific protein-like proteins between the cell membrane and the cytoskeleton, which affects the mitosis of the cells to have a good inhibitory activity against the major morphologies of the pathogen and has a good effect , Significantly different from fluazinam, metalaxyl, benzamide and methacrylic acid esters or other respiratory inhibitors such as imidazole. And plays a role in many stages of the life cycle of the bacteria, affecting the release of spores and the germination of spores. And in the xylem has a good mobility, with a very good internal absorption activity and protection treatment.
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Flupillotin was registered in the UK and China in 2005. In 2006, many countries in the world to obtain registration in 2008 in the United States and Japan were allowed to register. The species was launched in 2006, less than $ 30 million in 2009 and $ 45 million in 2011.
Ampicillinone
Japan’s Sumitomo Chemical research and development of pyrazolone fungicides, the pathogen of Botrytis, Sclerotinia and Sclerotinia sclerotiorum have a high degree of prevention and treatment. 2012 is listed under the trade name Botrycide in Korea for fruit and vegetables, followed by the European Union, the United States and New Zealand approved for grapes, almond trees, lettuce, certain fruit trees and landscape plants, against gray mold and other fungal diseases The 2016 under the trade name Prolectus was approved in Australia for grapes. Global sales in 2015 are $ 4 million.
Indolizine
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June 21, 2016, Japan’s Nissan Chemical Industry Co., Ltd. 50% indoxazolamide water dispersible granules in China to obtain temporary registration for the control of rice seedling blight and tobacco black shank. And the indoxazolidate 97.5% of the original drug and 18% of the suspension agent in China won the first board, means that Nissan Chemical this new fungicide officially stationed in the Chinese market.
The indazole sulfamate is a kind of triazole sulfonamide fungicide developed in the 1990s. It is also the first fungicide with independent intellectual property rights. The fungicide has a high activity against phytophthora and downy mildew caused by oomycetes. But so far, can effectively control the disease of the disease is not a lot of ochatidosis, the emergence of indazole sulfamethoxam to a certain extent, solve this problem. However, since indazole sulfamate does not have internal drawability, it is, in a strict sense, a protective fungicide, primarily for the prevention of disease.
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At present, indazole sulfamate registered crops mainly cucumber, grapes, potatoes and soybeans, for the control of such as cucumber downy mildew and potato late blight and other diseases. The use of indapoxazole is more flexible and can be used for foliar spray treatment, but also soil treatment and seed treatment. Most of the indoxazole products on the market were treated as foliar spray, such as Leimay; Oracle, which was used as a soil treatment, was first listed in Japan in 2010; Vortex used as seed treatment was mainly used for legume crops. From the use of dosage forms, there are mainly 17.7% indazole sulfamethoxazole suspensions, 50% indazole sulfamate water dispersible granules and 0.5% indazole sulfamate wettable powder. Formulations are mostly single-dose products, but there are also a small amount of complex preparations with mancozeb, cream cyanide or sterilized Dan.
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